Sintesis dan Uji Toksisitas Kompleks Tembaga(II) dengan Ligan [N,N’-Bis(Salisiliden)-1,2-Fenilendiamin]
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Institusion
Institut Teknologi Sepuluh Nopember
Author
Agustin, Irma Sofiana
Subject
QD Chemistry
Datestamp
2019-03-06 02:25:31
Abstract :
Ligan [N,N’-Bis(salisiliden)-1,2-fenilendiamin] dan senyawa kompleks Tembaga(II) dengan ligan [N,N’-Bis(salisiliden)-1,2-fenilendiamin]) berhasil di sintesis menggunakan refluks selama 2 jam. Ligan hasil sintesis berbentuk persegi panjang berwarna oranye cerah dengan rendemen sebesar 99,59%. Sedangkan senyawa kompleks hasil sintesis berbentuk balok kristal berwarna coklat dengan rendemen sebesar 31,66%. Hasil FTIR ligan menunjukkan puncak serapan pada 3446 dan 1612 cm-1. Sedangkan kompleks menunjukkan puncak pada 1608, 536, dan 397 cm-1. Hasil analisis UV-Vis menunjukkan perbedaan puncak antara ligan dan kompleks. Hasil MS menunjukkan massa relatif kompleks sebesar 377,8 m/z. Hasil BSLT menghasilkan nilai LC50 ligan sebesar 147,4396 ppm sedangkan nilai LC50 kompleks sebesar 183,5602 ppm. ================================================================================================ Copper(II) complex with [N,N’-bis(salicylidene)-1,2- phenylenediamine]ligand and it’s ligand had been synthesized using reflux for 2 hours. Orange crystall ligand had been collected with 99,59 % yield, and brown block crystall complex had been collected with 31,66 % yield. FTIR spectra of ligand showed characteristics peaks at wavenumbers 3446 and 1612 cm-1, but complex showed characteristics peaks at wavenumbers 1608, 536, dan 397 cm-1. UV-Vis spectra of ligand and complex has different peak. MS result showed the relative mass of complex is 377,8 m/z. Toxicity test was observed by Brine Shrimp Lethality Test (BSLT) method. The LC50 value of ligand is 147,4396 mg/L, and LC50 value of ligand is 183,5602 mg/L.
Ligan [N,N’-Bis(salisiliden)-1,2-fenilendiamin] dan senyawa kompleks Tembaga(II) dengan ligan [N,N’-Bis(salisiliden)-1,2-fenilendiamin]) berhasil di sintesis menggunakan refluks selama 2 jam. Ligan hasil sintesis berbentuk persegi panjang berwarna oranye cerah dengan rendemen sebesar 99,59%. Sedangkan senyawa kompleks hasil sintesis berbentuk balok kristal berwarna coklat dengan rendemen sebesar 31,66%. Hasil FTIR ligan menunjukkan puncak serapan pada 3446 dan 1612 cm-1. Sedangkan kompleks menunjukkan puncak pada 1608, 536, dan 397 cm-1. Hasil analisis UV-Vis menunjukkan perbedaan puncak antara ligan dan kompleks. Hasil MS menunjukkan massa relatif kompleks sebesar 377,8 m/z. Hasil BSLT menghasilkan nilai LC50 ligan sebesar 147,4396 ppm sedangkan nilai LC50 kompleks sebesar 183,5602 ppm. ================================================================================================ Copper(II) complex with [N,N’-bis(salicylidene)-1,2- phenylenediamine]ligand and it’s ligand had been synthesized using reflux for 2 hours. Orange crystall ligand had been collected with 99,59 % yield, and brown block crystall complex had been collected with 31,66 % yield. FTIR spectra of ligand showed characteristics peaks at wavenumbers 3446 and 1612 cm-1, but complex showed characteristics peaks at wavenumbers 1608, 536, dan 397 cm-1. UV-Vis spectra of ligand and complex has different peak. MS result showed the relative mass of complex is 377,8 m/z. Toxicity test was observed by Brine Shrimp Lethality Test (BSLT) method. The LC50 value of ligand is 147,4396 mg/L, and LC50 value of ligand is 183,5602 mg/L.
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